Hey there… are you sure your #5 bottle has been dispensing properly ?
This looks spot on to a Calcium deficiency, one of the most accurate depictions I’ve seen on AG compared to the pics:
Orange tips and burnt orange spots.
If your bottle #5 has been dispensing, you may potentially do a pH health check and make sure it’s calibrated. Maybe Calcium isn’t available if the pH reading is too high, but others like Nitrogen, Phosphorous, Potassium, and Magnesium are? Just spit balling.
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Just keep an eye on the spots though… make sure they aren’t progressing any worse or further up and you should be fine either way! I would still possibly investigate though, as I haven’t had a deficiency show up this bad in both my grows yet, knock on wood… only a few tiny little spots barely visible in pics.